Air pollutants emitted from chimneys of coal-fired power plants are considered to be a major source of fine particulate matter in the atmosphere. In order to manage fine particle in the chimney of a coal-fired power plant, it is necessary to know the concentration of fine particle emitted in real time, but the current system is difficult. In this study, a real-time measurement system for chimney fine particle was developed, and measurements were performed on six coal-fired power plants. Through the measurements, the mass concentration distribution according to the particle size could be secured. All six chimneys showed bimodal distribution, and the count median diameters of each mode were 0.5 and 1.1 μm. In addition, it was compared with the gravimetric measurement method, and it was determined that the relative accuracy for PM10 was within 20%, and the value measured using the developed measuring instrument was reliable. Finally, three power plants were continuously measured for one month, and as a result of comparing the concentration of PM10 according to the amount of power generation, it was confirmed that the PM10 discharged from the chimney increased in the form of an exponential function according to the amount of power generation.